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In situ transport measurements on epitaxial 7.6-nm-thick Co(0001)/Al2O3(0001) films with and without Ti and TiN capping layers during O2 exposure are used to investigate the effects of surface chemistry on electron scattering at Co(0001) surfaces. The Co sheet resistance Rs increases with increasing thickness dTi and dTiN of the Ti and TiN capping layers, saturating at 8% and 31% above the uncoated Co(0001) for dTi > 0.2 nm and dTiN > 0.1 nm, respectively. This increase is attributed to electron scattering into local surface states, which is less pronounced for Ti than TiN. In situ resistance measurements taken during a continuously increasing O2 partial pressure from 0 Pa to 40 Pa indicate a relatively steep 24% increase in Rs at an exposure of ∼50 Pa s, which can be attributed to Co surface oxidation that leads to atomic level roughness and a decrease in the electron scattering specularity p. Ti and TiN cap layers with dTi ≥ 0.5 nm and dTiN ≥ 0.13 nm exhibit no resistance change upon air exposure, indicating suppression of Co oxidation. These results indicate a promising Co–Ti interface with an electron scattering specularity of p = 0.4–0.5, which is retained during oxygen exposure, while, in contrast, electron scattering at the Co–TiN interface is completely diffuse (p = 0), suggesting that Ti barrier layers facilitate higher-conductivity Co interconnects than TiN barriers, as long as the Ti layer is sufficiently thick (dTi ≥ 0.5 nm) to suppress Co oxidation. 

Ru(0001) and Co(0001) films with thickness d ranging from 5 to 300 nm are sputter deposited onto Al2O3(0001) substrates in order to quantify and compare the resistivity size effect. Both metals form epitaxial single crystal layers with their basal planes parallel to the substrate surface and exhibit a root-mean-square roughness < 0.4 nm for Ru and < 0.9 nm for Co. Transport measurements on these layers have negligible resistance contributions from roughness and grain boundary scattering which allows direct quantification of electron surface scattering. The measured resistivity ρ vs d is well described by the classical Fuchs-Sondheimer model, indicating a mean free path for transport within the basal plane of λ = 6.7 ± 0.3 nm for Ru and λ = 19.5 ± 1.0 nm for Co. Bulk Ru is 36% more resistive than Co; in contrast, Ru(0001) layers with d ≤ 25 nm are more conductive than Co(0001) layers, which is attributed to the shorter λ for Ru. The determined λ-values are utilized in combination with the Fuchs-Sondheimer and Mayadas-Shatzkes models to predict and compare the resistance of polycrystalline interconnect lines, assuming a grain boundary reflection coefficient R = 0.4 and accounting for the thinner barrier/adhesion layers available to Ru and Co metallizations. This results in predicted 10 nm half-pitch line resistances for Ru, Co, and Cu of 1.0, 2.2, and 2.1 kΩ/µm, respectively.